dc.contributor.author | Hutchins, K.M. | |
dc.contributor.author | Rupasinghe, T.P. | |
dc.contributor.author | Ditzler, L.R. | |
dc.contributor.author | Swenson, D.C. | |
dc.contributor.author | Sander, J.R.G. | |
dc.contributor.author | Baltrusaitis, J. | |
dc.contributor.author | Tivanski, A.V. | |
dc.contributor.author | MacGillivray, L.R. | |
dc.date.accessioned | 2017-11-08T03:19:43Z | |
dc.date.available | 2017-11-08T03:19:43Z | |
dc.date.issued | 2014 | |
dc.identifier.citation | Hutchins, K.M., Rupasinghe, T.P., Ditzler, L.R., Swenson, D.C., Sander, J.R.G., Baltrusaitis, J., Tivanski, A.V., and MacGillivray, L.R., (2014). Nanocrystals of a Metal–Organic Complex Exhibit Remarkably High Conductivity that Increases in a Single-Crystal-to-Single-Crystal Transformation, American Chemical Society. Vol 136 (19). 6778-6781. | en_US |
dc.identifier.uri | http://repository.kln.ac.lk/handle/123456789/17955 | |
dc.description.abstract | Ag(I) is used to form a π-stacked metal–organic solid that exhibits remarkably high electrical conductivity. The solid undergoes a single-crystal-to-single-crystal [2+2] photodimerization to generate a 1D coordination polymer with over 40% higher conductivity. The Ag(I) complex represents the first example of an increase in conductivity resulting from a [2+2] photodimerization. Density of states calculations show a higher contribution from Ag(I) ions to the valence band in the photodimerized solid, supporting the increase in conductivity. | en_US |
dc.language.iso | en | en_US |
dc.publisher | American Chemical Society. | en_US |
dc.title | Nanocrystals of a Metal–Organic Complex Exhibit Remarkably High Conductivity that Increases in a Single-Crystal-to-Single-Crystal Transformation | en_US |
dc.type | Article | en_US |
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