| dc.contributor.author | Pandithavidana D R | en_US |
| dc.contributor.author | Poloukhtine A | en_US |
| dc.contributor.author | Popik V V | en_US |
| dc.date.accessioned | 2014-11-19T04:40:16Z | |
| dc.date.available | 2014-11-19T04:40:16Z | |
| dc.date.issued | 2009 | |
| dc.identifier.uri | http://repository.kln.ac.lk/handle/123456789/3792 | |
| dc.description.abstract | Irradiation of the nine-membered ring enediyne precursor, which has one of its triple bonds masked as cyclopropenone, efficiently (? = 0.34) generates the reactive 4,5-benzocyclonona-2,6-diynol. The latter rapidly equilibrates with the corresponding 1,4-didehydronaphthalene diradical and then undergoes rate-limiting hydrogen abstraction to produce the ultimate product of the Bergman cyclization, benz[f]indanol. | en_US |
| dc.publisher | Journal of the American Chemical Society | en_US |
| dc.title | Photochemical Generation and Reversible Cycloaromatization of a Nine-Membered Ring Cyclic Enediyne | |
| dc.type | article | en_US |
| dc.identifier.department | Chemistry | en_US |
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