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A Cu2O/TiO2 heterojunction thin film cathode for photoelectrocatalysis

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dc.contributor.author Siripala, W. en_US
dc.contributor.author Ivanovskaya, A. en_US
dc.contributor.author Jaramillo, T.F. en_US
dc.contributor.author Baeck Sung-Hyeon en_US
dc.contributor.author McFarland, E.W. en_US
dc.date.accessioned 2014-11-19T04:44:37Z
dc.date.available 2014-11-19T04:44:37Z
dc.date.issued 2003
dc.identifier.issn 0927-0248 en_US
dc.identifier.uri http://www.researchgate.net/publication/223850493_A_Cu2OTiO2_heterojunction_thin_film_cathode_for_photoelectrocatalysis
dc.description.abstract A thin film heterojunction photocathode was developed consisting of 100nm of n-type titanium dioxide (TiO2) cathode surface deposited on p-type cuprous oxide (Cu2O). The cuprous oxide was deposited electrochemically on Ti foil. A photocurrent of 0.7mA/cm2(at -1V bias) and an open circuit photovoltage of 460mV were obtained under an illumination of 700W/m2. The photoresponse as a function of pH demonstrated that the TiO2 film protected the Cu2O underlayer against corrosion. These results suggest that using a simple and inexpensive heterostucture configuration, the corrosion limitations of Cu2O alone may be overcome while maintaining a relatively high efficiency for photoelectrolysis. en_US
dc.publisher Solar Energy Materials and Solar Cells en_US
dc.subject Photocatalyst; Hydrogen; Photoelectrode; Heterojunction photocathode en_US
dc.title A Cu2O/TiO2 heterojunction thin film cathode for photoelectrocatalysis
dc.type article en_US
dc.identifier.department Physics en_US


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